Jumbo Team's Van Aert produced a powerful sprint in the slight uphill finish to win by half a wheel ahead of Cees Bol and Sam Bennett.
Fiorentina loanee Pedro put the visitors ahead in just the second minute by pouncing on an errant pass and sliding home from close range.
Garcia looked untouchable in the first set and for much of the second, blasting 30 winners and breaking Pliskova's serve three times en route to the 6-1, 7-6 (2) victory.
Garcia now faces No. 28 seed Jennifer Brady of the United States as she looks to reach the round of 16 for the first time. Enditem
Under the terms of the four-year agreement, TCL is granted exclusivity in the categories of home appliances including TVs, refrigerators, washing machines and air conditioners.
Fourth seed Naomi Osaka of Japan booked her place in the third round with a comfortable 6-1, 6-2 win over Italy's Camila Giorgi.
With Ajax, Van de Beek won the Eredivisie and the KNVB Cup in 2019 and made it to the semifinals of that year's UEFA Champions League. The midfielder has also been capped 10 times for the Dutch national team. Enditem
Rondon continued to demonstrate his prowess in the second half. In the 48th minute, the Venezuelan striker assisted Swedish winger Sam Larsson to stretch the lead for Dalian.
Australia, Norway and New Zealand are among other countries and regions to provide equal pay to their men's and women's teams.
Valter, 22, broke free during the final few kilometers and the peloton was unable to catch him.
"I tried to leave last year, but they blocked everything at the last second. It was a project I was excited for but it didn't materialize."